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An oil spill is the release of a liquid petroleum hydrocarbon into the environment due to human activity, and is a form of pollution. The term often refers to marine oil spills, where oil is released into the ocean or coastal waters. The oil may be a variety of materials, including crude oil, refined petroleum products (such as gasoline or diesel fuel) or by-products, ships' bunkers, oily refuse or oil mixed in waste. Spills take months or even years to clean up. Oil also enters the marine environment from natural oil seeps.[1] Most human-made oil pollution comes from land-based activity, but public attention and regulation has tended to focus most sharply on seagoing oil tankers.
The oil penetrates and opens up the structure of the plumage of birds, reducing its insulating ability, and so making the birds more vulnerable to temperature fluctuations and much less buoyant in the water. It also impairs birds' flight abilities, making it difficult or impossible to forage and escape from predators. As they attempt to preen, birds typically ingest oil that covers their feathers, causing kidney damage, altered liver function, and digestive tract irritation. This and the limited foraging ability quickly causes dehydration and metabolic imbalances. Hormonal balance alteration including changes in luteinizing protein can also result in some birds exposed to petroleum.[2] Most birds affected by an oil spill die unless there is human intervention.[3][4]
Marine mammals exposed to oil spills are affected in similar ways as seabirds. Oil coats the fur of Sea otters and seals, reducing its insulation abilities and leading to body temperature fluctuations and hypothermia. Ingestion of the oil causes dehydration and impaired digestions.
Because oil floats on top of water, less light penetrates into the water, limiting the photosynthesis of marine plants and phytoplankton. This, as well as decreasing the fauna populations, affects the food chain in the ecosystem.
A sheen is usually dispersed (but not cleaned up) with detergents which makes oil settle to the bottom. Oils that are denser than water, such as Polychlorinated biphenyls (PCBs), can be more difficult to clean as they make the seabed toxic.
Methods for cleaning up include:
Equipment used includes:[8]
Environmental Sensitivity Index (ESI) maps are used to identify sensitive shoreline resources prior to an oil spill event in order to set priorities for protection and plan cleanup strategies. By planning spill response ahead of time, the impact on the environment can be minimized or prevented. Environmental sensitivity index maps are basically made up of information within the following three categories: shoreline type, and biological and human-use resources[12].
Shoreline type is classified by rank depending on how easy the oil would be to cleanup, how long the oil would persist, and how sensitive the shoreline is [13]. The floating oil slicks put the shoreline at particular risk when they eventually come ashore, covering the substrate with oil. The differing substrates between shoreline types vary in their response to oiling, and influence the type of cleanup that will be required to effectively decontaminate the shoreline. In 1995, the National Oceanic and Atmospheric Administration extended ESI maps to lakes, rivers, and estuary shoreline types [12]. The exposure the shoreline has to wave energy and tides, substrate type, and slope of the shoreline are also taken into account â in addition to biological productivity and sensitivity. The productivity of the shoreline habitat is also taken into account when determining ESI ranking [14]. Mangroves and marshes tend to have higher ESI rankings due to the potentially long-lasting and damaging effects of both the oil contamination and cleanup actions. Impermeable and exposed surfaces with high wave action are ranked lower due to the reflecting waves keeping oil from coming onshore, and the speed at which natural processes will remove the oil.
Habitats of plants and animals that may be at risk from oil spills are referred to as âelementsâ and are divided by functional group. Further classification divides each element into species groups with similar life histories and behaviors relative to their vulnerability to oil spills. There are eight element groups: Birds, Reptiles and Amphibians, Fish, Invertebrates, Habitats and Plants, Wetlands, and Marine Mammals and Terrestrial Mammals. Element groups are further divided into sub-groups, for example, the âmarine mammalsâ element group is divided into dolphins, manatees, pinnipeds (seals, sea lions & walruses), polar bears, sea otters and whales[12][14]. Issues taken into consideration when ranking biological resources include the observance of a large number of individuals in a small area, whether special life stages occur ashore (nesting or molting), and whether there are species present that are threatened, endangered or rare[15].
Human use resources are divided into four major classifications; archaeological importance or cultural resource site, high-use recreational areas or shoreline access points, important protected management areas, or resource origins[12][15]. Some examples include airports, diving sites, popular beach sites, marinas, natural reserves or marine sanctuaries.
By observing the thickness of the film of oil and its appearance on the surface of the water, it is possible to estimate the quantity of oil spilled. If the surface area of the spill is also known, the total volume of the oil can be calculated.[16]
Oil spill model systems are used by industry and government to assist in planning and emergency decision making. Of critical importance for the skill of the oil spill model prediction is the adequate description of the wind and current fields. There is a worldwide oil spill modelling (WOSM) program.[17]
a One tonne of crude oil is roughly equal to 308 US gallons, or 7.33 barrels.
b Shown for comparison
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